Let's say that an $R$-module $W$ has the double commutant property if $C_W(C_W(R))$ equals the image of $R$ in $End(W)$.
I'll give a proof via Jordan decomposition. One consequence of Jordan decomposition is: if we view $V$ as a $\mathbb{C}[x]$-module, then there exists a direct sum decomposition
$$ V = V_1 \oplus \cdots \oplus V_n$$
into cyclic $\mathbb{C}[x]$-modules, i.e. for all $i$ there exists $v_i \in V_i$ such that $V_i = \mathbb{C}[x]v_i$.
Lemma 1: If $W$ is a cyclic $R$-module and $R$ is a commutative ring, then $C_W(R)$ is the image of $R$ in $End(W)$.
Proof: say $\varphi: W \to W$ intertwines $R$. If $v$ is the cyclic vector, then $\varphi(w) = rw$ for some $r \in R$. Then $\varphi(sw) = s\varphi(w) = srw = rsw$,
so since $W = Rw$, we conclude that $\varphi$ is left-multiplication by $r$. Since $R$ is commutative, the reverse holds.
Lemma 2: If $W_1$ and $W_2$ are $R$-modules, then for $V = W_1 \oplus W_2$, $$C_V(C_V(R)) \subseteq C_{W_1}(C_{W_1}(R)) \oplus C_{W_2}(C_{W_2}(R)).$$
Proof: Suppose that $T: V \to V$ lies in $C_V(C_V(R))$. We can write $T$ uniquely as $T = T_{11} + T_{12} + T_{21} + T_{22}$ where $T_{ij} \in Hom(W_j,W_i)$. We aim to show that $T_{12} = 0$, $T_{21} = 0$, and that $T_{11}$ and $T_{22}$ lie in their respective double commutants.
Let $V = W_1 \oplus W_2$. By definition of direct sum, the structure maps
$$ \pi_1: W_1 \oplus W_2 \to W_1 \to W_1 \oplus W_2 \qquad \pi_2: W_1 \oplus W_2 \to W_2 \to W_1 \oplus W_2$$
lie in $C_V(R)$. Then $\pi_1 T = T\pi_1$ since $T$ lies in the double commutant. Expanding into the direct sum $Hom(V,V) = \oplus_{ij} Hom(W_j,W_i)$ gives that $T_{11} + T_{12} = T_{11} + T_{21}$, implying that $T_{12} = 0$ and $T_{21} = 0$.
We may also observe that $C_{W_i}(R) \subseteq \oplus_{ij} Hom(W_j,W_i)$ is also contained in $C_V(R)$. If $\varphi_i \in C_{W_i}(R)$, then as $T$ is in the double commutant of $V$, $\varphi_iT_{ii} = T_{ii}\varphi_i$. Hence $T_{ii}$ is in the double commutant of $W_i$, as desired.
Now we can prove the desired result. Jordan decomposition states more than that we have a decomposition of $V$ into cyclic $\mathbb{C}[x]$-modules, but that we may in fact decompose into Jordan blocks, i.e. modules of the form $\mathbb{C}[x]/(x-\lambda)^n$. We will use these blocks to refine the inclusion in Lemma 2.
Lemma 3: If $V$ is a direct sum of Jordan blocks with the same eigenvalue, then $V$ has the double commutant property.
Proof: By replacing $x$ with $x -\lambda$, we may assume that the Jordan blocks have eigenvalue $0$, i.e. that $x$ acts nilpotently. Say that
$V = \oplus_i V_i$ where $V_i = \mathbb{C}[x]/x^{n_i}$, and without loss of generality that $n_i \geq n_{i+1}$ for all $i$. Suppose that $T \in C_{V}(C_{V}(\mathbb{C}[x]))$; by Lemma 2, we may write $T = \oplus T_{ii}$ for $T_{ii} \in C_{V_i}(C_{V_i}(\mathbb{C}[x]))$.
Now since $n_i \geq n_{i+1}$ for all $i$, we have $\mathbb{C}[x]$-module surjections
$$ s_{i1}: \mathbb{C}[x]/x^{n_1} \to \mathbb{C}[x]/x^{n_i},$$
which may be viewed as maps $s_{i1}: V \to V$ by composing with the structure maps for the direct sum. Then $s_{i1} \in C_V(\mathbb{C}[x])$, so we have $s_{1i}T = Ts_{1i}$ for all $i$. Hence, $s_{i1}T_{11} = T_{ii}s_{i1}$. By Lemma 1, $C_{V_1}(C_{V_1}(\mathbb{C}[x])) = \mathbb{C}[x]/x^{n_1}$. So if $T_{11} = p(x)$, then
$$ T_{ii}s_{i1} = s_{i1}T_{11} = s_{i1}p(x) = p(x)s_{i1}.$$
Since $s_{i1}$ is surjective, we conclude $T_{ii} = p(x)$ as well (as an endomorphism of $V_i$). As this holds for all $i$, $T = p(x)$ (as an endomorphism of $V$).
Lemma 4: If $W_1$ and $W_2$ are $\mathbb{C}[x]$-modules with the double commutant property and the minimal polynomials $r_1$ and $r_2$ of $x$ on $W_1$ and $W_2$ are coprime, then $W_1 \oplus W_2$ has the double commutant property.
Proof: Let $V = W_1 \oplus W_2$. By Lemma 2, if $\pi_i: W_1 \oplus W_2 \to W_i \to W_1 \oplus W_2$ are the structure maps, then
$$ C_V(C_V(\mathbb{C}[x])) \subseteq \mathbb{C}[x]\pi_1 \oplus \mathbb{C}[x]\pi_2.$$
It suffices to show that any transformation $V \to V$ of the form $p_1(x) \pi_1 + p_2(x) \pi_2$ is in the image of $\mathbb{C}[x]$ in $End(V)$. So it suffices to show that $\pi_1$ and $\pi_2$ are in the image of $\mathbb{C}[x]$.
Since $r_1$ and $r_2$ are coprime, there exist polynomials $f_1, f_2$ such that
$$f_1r_1 + f_2r_2 = 1.$$
Then $f_1r_1(x)= 1 - f_2r_2(x)$ acts as zero on $V_1$ and as the identity on $V_2$, so it acts as $\pi_2$ on $V$. This shows that $\pi_2$ and thus $\pi_1 = 1 - \pi_2$ are in the image of $\mathbb{C}[x]$, as desired.
Theorem: Any finite-dimensional $\mathbb{C}[x]$-module $V$ has the double commutant property.
Proof: By Jordan decomposition, we may decompose $V$ into summands $V_1\oplus\cdots \oplus V_n$ where $x$ acts with a single eigenvalue on each block. By Lemma 3, each $V_i$ has the double commutant property. Then induct via Lemma 4 to show that $V_1 \oplus \cdots \oplus V_k$ has the double commutant property for all $k$, as the minimal polynomial of $x$ on $V_1 \oplus \cdots \oplus V_{k-1}$ and $V_k$ have no roots in common.