In either case it is easy enough to find all rational solutions by stereographic projection around a known solution, both have (1,1,1,1). Take a relatively prime quadruple $(p,q,r,s)$ and evaluate the quadratic form at
$$ (1,1,1,1) + t (p,q,r,s). $$
The first form is $3x^2 + y^2 - 2 z^2 - 2 w^2.$ The second is $3x^2 + 2 y^2 - z^2 - 4 w^2.$ In either case $t=0$ is always a solution, then there is a nonzero rational value for $t$ that gives a solution in that direction, and $t$ depends on the direction integers $(p,q,r,s).$
Give me a few minutes. Note that sorting out the primitive integral solutions is the real problem and harder.
Here is the calculation for the first using gp-pari. I will also typeset it. Before I do that, note that, even though we take $\gcd(p,q,r,s) = 1,$ it is still easy to get common factors in $(x,y,z,w).$ So, one half-satisfactory way to proceed is just to say "use these formulas and then divide out by any $\gcd(x,y,z,w).$" ADDED: I am not so sure the set of possible gcd's is finite with four variables. It is in three variables, goes back to Fricke and Klein (1897). I did a trial run with bounds on $p,q,r,s,$ the list of all gcds was:
0 1 2 3 4 6 8 9 11 12 13 16 18 22 23 24 25 26 27 32 33 36 37 39 44 46 47 48 49 50 52 54 64 66 72 74 75 78 81 88 92 94 96 98 100 104 108 118 121 122 128 132 138 142 144 146 147 148 162 166 169 184 192 196 200 222 242 243 256 288 300 324 338 363 392 400 432 484 507 576 588 676 784
$$ x = -3p^2 + q^2 - 2 r^2 - 2 s^2 - 2 pq + 4pr + 4ps \; , \; $$
$$ y = 3p^2 - q^2 - 2 r^2 - 2 s^2 - 6 pq + 4qr + 4qs \; , \; $$
$$ z = 3p^2 + q^2 + 2 r^2 - 2 s^2 - 6 pr -2qr + 4rs \; , \; $$
$$ w = 3p^2 + q^2 - 2 r^2 + 2 s^2 - 6 ps -2qs + 4rs \; , \; $$
See how, if we simply take $p=1$ and the others $0,$ we get $(-3,3,3,3)$ with a common factor of $3$
parisize = 4000000, primelimit = 500000
? d = 3 * p^2 + q^2 - 2 * r^2 - 2 * s^2
%1 = 3*p^2 + (q^2 + (-2*r^2 - 2*s^2))
? n = -6 * p - 2 * q + 4 * r + 4 * s
%2 = -6*p + (-2*q + (4*r + 4*s))
? x = d + n * p
%3 = -3*p^2 + (-2*q + (4*r + 4*s))*p + (q^2 + (-2*r^2 - 2*s^2))
? y = d + n * q
%4 = 3*p^2 - 6*q*p + (-q^2 + (4*r + 4*s)*q + (-2*r^2 - 2*s^2))
? z = d + n * r
%5 = 3*p^2 - 6*r*p + (q^2 - 2*r*q + (2*r^2 + 4*s*r - 2*s^2))
? w = d + n * s
%6 = 3*p^2 - 6*s*p + (q^2 - 2*s*q + (-2*r^2 + 4*s*r + 2*s^2))
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?
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? 3 * x^2 + y^2 - 2 * z^2 - 2 * w^2
%7 = 0
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