$\def\A{\mathbb A}$You can use the Lindemann-Weierstrass theorem to construct lots of such numbers:
If $α_j\in\A$ are distinct algebraic numbers, then the exponentials $e^{α_j}$ are linearly independent over $\A$.
Now chose $α_2=0$ and $a\neq0$ in such a way that $α_1=a\ln\pi$ is algebraic. Then 1 and $e^{α_1}=\pi^a$ are independent over $\A$, i.e. $\pi^a$ is transcendental and thus irrational.
Note: Dunno whether $\ln\pi$ is algebraic or not, at least that theorem does not contradict it because we know $\pi\in\A$: Assuming $\ln\pi\in\A$ would just yield 1and $\pi$ were independent over $\A$, hence no contradiction.