Note that $E$ is a field extension of $\mathbb{Q}(\sqrt{7})$ and hence we can use the tower rule:
$4\geq [E:\mathbb{Q}]=[E:\mathbb{Q}(\sqrt{7})][\mathbb{Q}(\sqrt{7}):\mathbb{Q}]=[E:\mathbb{Q}(\sqrt{7})]\times 2$
The element $\alpha$ does not belong to $\mathbb{Q}(\sqrt{7})$. In order to see this try to write $\alpha=a+b\sqrt{7}$ when $a,b\in\mathbb{Q}$ and you will get that $\sqrt{7}$ is rational which is of course a contradiction. Hence $[E:\mathbb{Q}(\sqrt{7})]$ is at least $2$, so that gives us $4\geq[E:\mathbb{Q}]\geq 4$ which of course implies $[E:\mathbb{Q}]=4$.
Ok, now you know that the extension is Galois of degree $4$. Hence $Gal(E/\mathbb{Q})$ is either $\mathbb{Z_4}$ or $\mathbb{Z_2}\times\mathbb{Z_2}$. However, if we denote $\beta=\sqrt{4-\sqrt{7}}$ then the roots of $f$ are $\alpha,-\alpha,\beta,-\beta$. Now, since the extension $E/\mathbb{Q}$ is simple and generated by $\alpha$ we know that for any $c\in E$ which is a root of the minimal polynomial of $\alpha$ there exists an element in $Gal(E/\mathbb{Q})$ which sends $\alpha\to c$. Hence there is an element in $Gal(E/\mathbb{Q})$ which sends $\alpha\to -\alpha$. Since $\beta=\frac{3}{\alpha}$ it is easy to see that this automorphism sends $\beta\to -\beta$, and hence it defines the permutation $(\alpha,-\alpha)(\beta,-\beta)$ on the roots of $f$. Also, there is an element in $Gal(E/\mathbb{Q})$ which sends $\alpha\to\beta$. Again, it is easy to check that such an automorphism must send $\beta\to\alpha$, and hence it defines the permutaiton $(\alpha,\beta)(-\alpha,-\beta)$. So $Gal(E/\mathbb{Q})$ contains at least two elements of order $2$ and this implies that it must be isomorphic to $\mathbb{Z_2}\times\mathbb{Z_2}$.