As Lord Shark the Unknown commented, since the numerator grows larger quicker than the denominator, we can simply use the divergence test to conclude that the series diverges.
$$\lim_{n\to \infty} \frac{n+3^n}{n+2^n} = \infty \neq 0 \Rightarrow \text{diverges}$$
A comparison test is also appropriate. As you noticed, you can compare your sequence to $\left(\frac{3}{2}\right)^n$. I would recommend a limit comparison test:
$$\lim_{n\to \infty} \frac{n+3^n}{n+2^n} \cdot \frac{2^n}{3^n} =\lim_{n\to \infty}\frac{n+3^n}{n+2^n}\cdot \frac{\frac{1}{3^n}}{\frac{1}{2^n}}= \lim_{n \to \infty} \frac{\frac{n}{3^n}+1}{\frac{n}{2^n}+1} =1$$
Since $0<1<\infty$, and $\sum\left(\frac{3}{2}\right)^n$ diverges, the original sum has the same behavior and diverges as well.