Several points.
1) CLT only gives approximation to normal, not equality.
2) While the standard CLT can be easily applied to the case where the parameter $\alpha$ is an integer tending to $\infty$, you have a slight problem if $\alpha_n \to \infty$ with $\alpha_n$ real; consider Douglas Zare's comment: the sequence of parameters $\alpha _n /\left\lfloor {\alpha _n } \right\rfloor $ is not fixed (though tends to $1$).
3) This problem is essentially a special case of this recent one
. Indeed, if $N$ has parameter $\alpha=t$, then it is equal in distribution to $X_t$, where $X = \{X_t: t \geq 0\}$ is a Poisson process with rate $1$. But $X$ is just a special case of a compound Poisson process, where the jump distribution is the $\delta_1$-distribution (this corresponds to the $Y_i$ being equal to $1$ in the linked post). So, instead of considering $\frac{{N - E(N)}}{{\sigma (N)}}$, you can consider $\frac{{X_t - E(X_t )}}{{\sigma (X_t )}}$ (which has been done in the linked post).
Remark. Note that in the linked post the $\frac{{X_t - E(X_t )}}{{\sigma (X_t )\sqrt {N_t } }} \to {\rm N}(0,1)$ appearing in question 1 should have been replaced with $\frac{{X_t - E(X_t )}}{{\sigma (X_t ) }} \to {\rm N}(0,1)$.