As an example of a banach space that is not reflexive we have $E=L^1(\Bbb R)$
As a proof I had this: $E=L^1(\Bbb R) \Rightarrow E'=L^{\infty}(\Bbb R) \Rightarrow E''\ne L^1(\Bbb R)$
I don't understand how the topological dual of $E$ is $L^{\infty}(\Bbb R)$ and why $E''\ne L^1(\Bbb R)$.
Thank you for your help.