Hint $\ $ Because one can divide with unique remainder by any monic polynomial $\rm\,f,\,$ the coset $\rm\: g +(f) \in R[x]/(f)\:$ may be uniquely represented by its least degree element, the remainder $\rm\:g\ mod\ f\, =\, g - hf.\:$ Therefore the polynomials of degree $\rm < deg\, f\,$ form a complete system of representatives of $\rm\,R[x]/(f).\,$ Thus we can represent the ring by these normal forms, and pullback the ring operations to the normal form reps (transport of structure), e.g. $\rm\: g * h := gh\ mod\ f.\:$
For example, Hamilton's presentation of $\Bbb C$ as pairs of reals is a special case $\:\Bbb R[i]\cong \rm\Bbb R[x]/(x^2\!+1).\:$ Here the normal forms are all linear polynomials ${\rm\:a + bx }\:$ with the transported multiplication
$$\rm\begin{eqnarray}\rm (a\! +\! bx)&&\rm(c\! +\! d x)\, &\rm\,\equiv\,&\rm (ac\!-\!bd) + (ad\!+\!bc)\, x\ \ \ (mod\ x^2\!+1)\\
\rm i.e.\quad (a\! +\! b{\it i}\,)&&\rm(c\! +\! d {\it i}\,)\, &\, =\,&\rm (ac\!-\!bd) + (ad\!+\!bc)\,{\it i}\end{eqnarray}$$
The same remainder representation works for any Euclidean domain with unique remainders, i.e. any domain with a division algorithm with unique smaller remainder, e.g. the familiar, case of of $\rm\,\Bbb Z/m = $ integers $\rm\,mod\ m,\,$ represented by $\,0\,$ and the least positive element of each nonzero coset $\rm\:k + m\,\Bbb Z\,\to\, k\ mod\ m,\:$ with transported multiplication $\rm\ j k\, :=\, jk\ mod\ m.$
There are multidimensional generalizations of the division algorithm (e.g. Grobner bases) which extend the above to certain multivariate polynomial rings $\rm\,R[x,y,z\ldots]/(f,g,h,\ldots).\:$
The above can be viewed as ring-theoretic special cases of very general methods in term rewriting systems for solving word problems in (quotient) equational algebras, e.g. the Knuth-Bendix completion algorithm. For more on the ring-theoretic perspective see George Bergman's classic paper: The diamond lemma for ring theory, 1978. and its errata and updates. Chasing links to this will locate recent literature on these topics (generalizations of Grobner bases, etc).