I'm modeling my solution after this answer to a similar question. This is as far as I've gotten:
Every $\phi \in \mathcal{S}(\mathbb{R})$ that vanishes at $0$ can be expressed as $\phi(x) = x \psi (x)$. Then, $T\phi = xT(\psi) = 0$ by assumption.
Fix $\chi \in \mathcal{S}(\mathbb{R})$ such that $\chi(0) = 1$. Let $T\chi = a$. Then, for any $\phi \in \mathcal{S}(\mathbb{R})$, $$T\phi = T(\phi - \phi(0) \chi + \phi(0) \chi) = T(\phi - \phi(0) \chi) + T(\phi(0) \chi).$$
This is where I've gotten stuf. I'm not sure how, in the linked solution, the answer reduces from $T(\phi - \phi(0) \chi) + T(\phi(0) \chi)$ to $0 + a \phi(0)$ (my primary confusion is $T(\phi - \phi(0) \chi) = 0$) nor how to adapt that for my own question.
Any suggestions?