Write $K = \{(r, s) \colon r, s \in \mathbb{N}, \ r \geqslant 2s\}$. The functions:
\begin{align*}
& f \colon \mathbb{N}^2 \to K, \ (p, q) \mapsto (2p + q, p), \\
& g \colon K \to \mathbb{N}^2, \ (r, s) \mapsto (s, r - 2s)
\end{align*}
are mutually inverse bijections. Therefore, if the family $(a(p, q))_{p, q \in \mathbb{N}}$ is absolutely summable [see below]:
$$
\sum_{p=0}^\infty\sum_{q=0}^\infty a(p,q) =
\sum_{p, q \in \mathbb{N}}a(p, q) =
\sum_{(r, s) \in K} a(s, r - 2s) =
\sum_{r=0}^\infty\sum_{s=0}^{\lfloor{r/2}\rfloor} a(s,r-2s).
$$
The first and third equalities follow from Dieudonne, Foundations of Modern Analysis (1969), proposition (5.3.6):
Let $(x_\alpha)_{\alpha \in A}$ be an absolutely summable family of elements of a Banach space $E$. Let $(B_n)$ be an infinite sequence of nonempty subsets of $A$, such that $A = \bigcup_nB_n$, and $B_p \cap B_q = \emptyset$ for $p \ne q$; then, if $z_n = \sum_{\alpha \in B_n}x_\alpha$ [it has already been shown that such a sum is well-defined], the series $(z_n)$ is absolutely convergent, and $$\sum_{n=0}^\infty z_n = \sum_{\alpha \in A}x_\alpha$$ ("associativity" of absolutely convergent series).
As for the second equality, quoting Dieudonne again:
Let $A$ be any denumerable set. We say that a family $(x_\alpha)_{\alpha \in A}$ of elements of a Banach space $E$ is absolutely summable if, for a bijection $\varphi$ of $\mathbb{N}$ onto $A$, the series $(x_{\varphi(n)})$ is absolutely convergent; it follows from [the rearrangement theorem for absolutely convergent series] that this property is independent of the particular bijection $\varphi$, and that we can define the sum of the family $(x_\alpha)_{\alpha \in A}$ as $\sum_{n=0}^\infty x_{\varphi(n)}$, which we write $\sum_{\alpha \in A}x_\alpha$.
Clearly, therefore, if $f \colon A \to B$ and $g \colon B \to A$ are mutually inverse bijections, and we put $y_\beta = x_{g(\beta)}$ ($\beta \in B$), so that also $x_\alpha = y_{f(\alpha)}$ ($\alpha \in A$), then the family $(x_\alpha)_{\alpha \in A}$ is absolutely summable if and only if the family $(y_\beta)_{\beta \in B}$ is absolutely summable; and in that case, $\sum_{\alpha \in A}x_\alpha = \sum_{\beta \in B}y_\beta$.