Seeking contradiction assume that $A_4$ has a subgroup of order $6$. Clearly all elements of $A_4$ have order $1$, $2$ or $3$. Thus the subgroup of order $6$ cannot be cyclic. Thus it must be isomorphic to $S_3$. In particular it must have two elements of order $3$ and three elements of order $2$.
I show that if $h$ is any element of $A_4$ of order $3$ and $g$ any element of $A_4$ of order $2$, then $hg$ is of order $3$.
First $hg$ cannot be of order $1$. Since that would mean that $h = g^{-1}$. And since the order of the inverse is the same as that of the element, this would imply that $h$ and $g$ have the same order.
Further, $hg$ cannot have order $2$. Let's assume, for the sake of contradiction that it does. Let's name $h_1$, $h_2$ and $h_3$ any distinct elements of $A_4$ of order $3$. And $g$ any one of the three elements of $A_4$ of order $2$. Then $h_1g$, $h_2g$ and $h_3g$ are $3$ distinct elements such that $h_1g \neq g$ and $h_2g \neq g$ and $h_3g \neq g.$ By our assumption each of $h_1g$, $h_2g$ and $h_3g$ have order $2$. Since none of them equal to $g$ we have four elements of order $2$. But $A_4$ has only three elements of order $2$. This is a contradiction. Also, $hg$ cannot have order greater than $3$ since no element of $A_4$ has order greater than $3$.
Let's give the elements of our subgroup names: $e$, $m_1$, $m_2$ and $k_1$, $k_2$, $k_3$. The m's are the two elements of order $3$ and k's are the three elements of order $2$.
Finally $m_1k_1$, $m_1k_2$ and $m_1k_3$ are three distinct elements of our subgroup of order $3$. But this is a contradiction with the fact that the subgroup has only two elements of order $3$. Thus $A_4$ cannot have a subgroup of order $6$.