First, rewrite the summand as $$\frac{1}{4^n (2n-1)} \binom{2n}{n} = \frac{(2n)!}{4^n (2n-1)n! n!} = \frac{2 (2n-2)!}{4^n n! (n-1)!} = \frac{2}{4^n n} \binom{2(n-1)}{n-1}.$$
Switching indices on the sum, you're trying to find
$$\sum_{n=0}^{\infty} \frac{2}{4^{n+1} (n+1)} \binom{2n}{n} = \frac{1}{2}\sum_{n=0}^{\infty} \frac{1}{4^n (n+1)} \binom{2n}{n}$$
Since the $n$th Catalan number is $\binom{2n}{n} \frac{1}{n+1},$ what you need now is the generating function for the Catalan numbers. This is
$$\sum_{n=0}^{\infty} \binom{2n}{n} \frac{z^n}{n+1} = \frac{1 - \sqrt{1-4z}}{2z}.$$
With $z = 1/4$, we have
$$\frac{1}{2}\sum_{n=0}^{\infty} \frac{1}{4^n (n+1)} \binom{2n}{n} = \frac{1}{2}\frac{1 - \sqrt{1-1}}{1/2} = 1.$$
Added: There's a probabilistic interpretation here, too. Imagine two players playing a game in which each flips a fair coin once per round. They stop when they have accumulated exactly the same number of heads. Then the probability that the game ends in round $n$ is precisely the summand $$\frac{2}{4^n n} \binom{2(n-1)}{n-1} = \frac{2}{4^n} C_{n-1},$$
with $C_n$ the $n$th Catalan number. (See, for example,
my answer here.) The fact that the OP's infinite series sums to $1$ indicates that the game will end with probability $1$.