Suppose it were true. What could the functions possibly be?
Let $f(x) = g(x) + h(x)$ where $g$ is even and $h$ is odd.
Then $f(-x) = g(x) - h(x)$
And $f(x)+f(-x) = 2g(x)$. and so $g(x) = \frac {f(x) + f(-x)}2$.
The is indeed an even function that will work, and is apparently a unique such even function.
If we can verify that $h(x) =f(x) - g(x)$ is odd we will have found that not only is this possible, but we will have found a unique odd/even pair for which this can be true.
Now $h(x)= f(x) - g(x) = f(x) - \frac {f(x) + f(-x)}2 = \frac {f(x) - f(-x)}2$ is indeed an odd function.
So we are done:
$f(x) = g(x) + h(x)$ where $g$ is even and $h$ is odd is uniquely expressed when $g(x) = \frac {f(x) + f(-x)}2$ and $h(x) = \frac {f(x) - f(-x)}2$.