I'm assuming, based on your tags, that we are treating $G$ as an additive group. In that case, $G$ is the set of 2-tuples with entries in $\mathbb{Z}$, and the group action of addition. $H$ is a subgroup of $G$, where we are restricted to the tuples in which both entries are the same.
Hence, in $G/H$, anything in the form $(a,a)$ is equal to zero. Hence, if we take an arbitrary element $(x,y) \in G$, then, in $G/H$, we have
$$(x,y) = (x,y)-(y,y) = (x-y,0)$$
because $(y,y) = 0$ in this quotient. Since we can pick $x$,$y$ so that $x-y$ is any integer, we see that this suggests that $G/H \cong \mathbb{Z}$.
Now, to formally prove this, we can consider the map from $G$ to $\mathbb{Z}$ that takes $(x,y) \to x-y$, and prove that the kernel is equal to $H$.
In general, to determine these quotients, you should try playing around with the relations given by the group you're quotienting over. Then, to make a formal argument, you should construct functions onto the space that you have determined to be the quotient, and show that $H$ is the kernel.