The hypothesis that $n$ be positive composite implies
$n \ge 4; \tag 1$
thus
$n - 1 \ge 3; \tag 2$
if
$n - 1 \mid n, \tag 3$
there exists $k \in \Bbb Z$ with
$n = k(n - 1); \tag 4$
since
$n, n - 1 \ge 3, \tag 5$
we must have
$k \ge 2; \tag 6$
indeed, $k$ cannot be negative or zero by (4),(5); it cannot be $1$ since $n \ne n - 1$; also,
$k < n, \tag 7$
for if
$k \ge n, \tag 8$
then
$n = k(n - 1) \ge n(n - 1) \ge 3n > n, \tag 9$
impossible.
Then, from (4),
$n = nk - k, \tag{10}$
or
$k = nk - n = (k - 1)n \ge n, \tag 8$
contradicting (7); thus no such $k$ exists, and hence
$n - 1 \not \mid n. \tag 9$