If I could guess, I would say it's not. But how to prove it?
It's know that $\sin a$ is transcendental, therefore irrational for $a$ algebraic. This is a result from Lindemann–Weierstrass theorem. Knowing this we can prove that $\arcsin a$ is also transcendental for a algebraic argument. But what about a sum, eg. $\arcsin 1/4$ + $\arcsin 1/3$.
Or $\arcsin a + \arcsin b$, for algebraic $a$ and $b$.
I found another way, but I'm not sure if it's correct.
One can show that: $\arcsin x = -i \ln(\sqrt{1-x^2}+ix)$. So,
$\arcsin a + \arcsin b = -i \ln(\sqrt{1-a^2}+ia) -i \ln(\sqrt{1-b^2}+ib) $.
$\arcsin a + \arcsin b = -i \ln[ (\sqrt{1-a^2}+ia)(\sqrt{1-b^2}+ib)] $
If $a$ and $b$ are algebraic, so it is $(\sqrt{1-a^2}+ia)(\sqrt{1-b^2}+ib)$.
Another result of Lindemann–Weierstrass theorem is that $\ln a$ is transcendental for $a$ algebraic. So for $a$ and $b$ algebraic, $\arcsin a + \arcsin b$ is transcendental.