First, you want to show that $R$ satisfies the ring axioms. That is
- $(R,+)$ is an abelian group.
- Multiplication is associative.
- Multiplication is distributive with respect to addition.
You can show 1. by showing that i) addition is associative, ii) addition is commutative, iii) there exists an additive identity, and iv) there exists additive inverses.
Let $A,B,C \in R$, and let $A^C$ denote the compliment of $A$.
i) The operation $+$ defined by $A+B = (A\setminus B)\cup(B\setminus A)$ is commonly referred to as the "symmetric difference" and the (lengthy) proof of associativity is shown here: https://proofwiki.org/wiki/Symmetric_Difference_is_Associative
ii) Addition is commutative.
Since $\cup$ is commutative, $A+B = (A\setminus B)\cup(B\setminus A) = (B\setminus A)\cup(A\setminus B) = B+A$.
iii) Additive identity.
Suppose $0_R = \emptyset$. Then for any $A \in R$,
$A + 0_R = (A\setminus \emptyset)\cup(\emptyset \setminus A) = (A\cap \emptyset^C)\cup(\emptyset \cap A^C) = (A\cap U)\cup(\emptyset \cap A^C) = A\cup \emptyset=A$.
Since $+$ is commutative, it follows that $0_R + A = A + 0_R = A.$
iv) Additive inverses.
Suppose $(-A) = A$. Then for any $A \in R$,
$A + (-A) = A + A = (A\setminus A)\cup(A\setminus A) = (A\cap A^C)\cup(A\cap A^C) = \emptyset \cap\emptyset = \emptyset = 0_R$.
2) Multiplication is associative.
Since $\cap$ is associative, $A(BC) = A\cap(BC) = A\cap(B\cap C) = (A\cap B)\cap C = (AB)C$.
3) Multiplication is distributive with respect to addition.
\begin{align}
A(B+C) &= A\cap(B+C) \\
&= A\cap((B\setminus C)\cup(C\setminus B)) \\
&= (A\cap(B\setminus C))\cup(A\cap(C\setminus B)) \\
&= (A\cap B\cap C^C)\cup(A\cap C\cap B^C) \\
&= ((A\cap B)\cap (C^C\cup A^C))\cup((A\cap C)\cap (B^C\cup A^C)) \\
&= ((AB)\cap(AC)^C)\cup((AC)\cap(AB)^C) \\
&= AB + AC
\end{align}
Now all you need to show is that the ring $R$ is also a Boolean ring, which is simple since
$A^2 = AA = A\cap A = A$.