$$\frac{1}{1^2} + \frac{1}{2^2} + \frac{1}{3^2} + \frac{1}{4^2} + \frac{1}{5^2} + \cdots=\frac{\pi^2}{6}$$
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$$1-\frac12+\frac13-\frac14+\frac15-\cdots=\ln(2)$$
There are many examples of this, because many of the irrational numbers we like to talk about are values of transcendental functions, which can often be written as power series, so for example:
$$e^x=1+x+\frac{x^2}{2!}+\frac{x^3}{3!}+\frac{x^4}{4!}+\cdots$$
and this particular equation works no matter what value of $x$ we plug in. Thus, plugging in $x=1$:
$$1+1+\frac1{2!}+\frac1{3!}+\frac{1}{4!}+\cdots=e^1=e$$
If you plug in a different rational $x$, you'll get another irrational number: $e^x$, written as a sum of rational fractions. (To be a bit more precise, $e^x$ is irrational for any non-zero rational $x$.) That's just one function that produces such series representations, and that's not the only way to obtain sums like these.
It's worth mentioning that every irrational number can be written as a sum of rational fractions. For example:
$$3+\frac{1}{10}+\frac{4}{100}+\frac{1}{1000}+\frac{5}{10000} + \cdots = \pi$$
There might not be a nice obvious pattern to the numerators, but it still should count, as it seems to meet the requirement.