A Formal system is made of:
(i) a language, made of
(i.a) an alphabet: a set (usually finite) of symbols, and
<p><em>(i.b)</em> a <em>grammar</em>: a set of rules which tell how some expressions are <em>well-formed</em> (i..e. meaningful);</p>
and:
(ii) a proof system (or calculus), made of
(ii.a) a set of "special" formulas: the axioms, and
<p><em>(ii.b)</em> a set of <em>inference rules</em>.</p>
First-order logic (or predicate calculus) is a proof system based on first-order language, i.e. the language having as logical symbols, in addition to the (propositional) connectives, also the quantifiers and the (individual) variables.
It is called "first-order" because quantification is allowed on individual variables only.
When quantification is allowed also on predicate variables, we call it Higher-order logic.