I expect that you know what a chain in the partial order $\langle P,\le\rangle$ is: a subset of $P$ that is linearly ordered by $\le$. A maximal chain is simply a chain that is not a proper subset of any other chain. For example, if you partially order the positive integers by divisibility (i.e., $m\le n$ iff $m\mid n$), then $C=\{2^k:k\in\Bbb N\}$ is a maximal chain: if you add to $C$ any positive integer that is not a power of $2$, you’ll no longer have a chain. Thus, you’re being asked to find a countable partial order that has $|\Bbb R|$ distinct maximal chains.
It is perhaps a little surprising that it’s possible to find such a small partial order with so many different chains, so it’s not surprising that an example probably isn’t immediately obvious. I’ve given a couple of (very similar) examples below, leaving the verification that they work to you; if you want to try finding one on your own, you should stop reading here.
Let $P$ be the set of finite sequences of $0$’s and $1$’s, setting $\sigma\le\tau$ if and only if $\sigma$ is an initial segment of $\tau$. Show that there is a maximal chain for each infinite sequence of $0$’s and $1$’s.
Alternatively, let $\mathscr{F}$ be the family of finite subsets of $\Bbb N$, and define the partial order $\le$ as follows: for $F,G\in\mathscr{F}$, $F\le G$ if and only if $F\subseteq G$ and either $F=G$ or $\max F<\min(G\setminus F)$. In other words, if $F$ and $G$ are distinct members of $\mathscr{F}$, then $F<G$ if and only if $F\subseteq G$ and every element of $G\setminus F$ is larger than every element of $F$. Show that there is a maximal chain in $\langle\mathscr{F},\le\rangle$ for each infinite subset of $\Bbb N$. (This partial order is isomorphic to the subset of the first one consisting of those finite sequences whose last terms are $1$.)