The second property is that the inner measure of $E$
$$\mu _{*}(E)=\sup\{\mu (S):S {\text{ measurable and }}S\subseteq E\}$$
is zero. "Meagre" is already a standard term meaning something quite different, see meagre set. (A Vitali set happens to be non-meagre in this sense, since a countable union of Vitali sets contains $[0,1]$ which has non-empty interior.)
The inner measure of a Vitali set is in fact zero, by essentially the same argument as the usual argument that it is non-measurable: suppose $\mu(S)>0$ where $S$ is a measurable subset of a Vitali set.
By construction of the Vitali set, the sets $S+q$ are disjoint for distinct $q\in \mathbb Q$, so by countable additivity of Lebesgue measure (for measurable sets), $\mu(\bigcup_{q\in [0,1]\cap\mathbb Q} (S+q))=\infty$, which contradicts monotonicity because $\bigcup_{q\in [0,1]\cap\mathbb Q} (S+q)\subseteq [0,2]$.
More generally any non-measurable set $E\subseteq[0,1]$ can be used to give a non-measurable set with inner measure zero. Take a sequence of measurable sets $S_n\subseteq E$ with $\mu(S)\geq \mu_*(E)-1/n$, which exist by definition of the supremum. Defining $S=\bigcup_{n\geq 1} S_n$ we find that $\mu(S)=\mu_*(E)$. And $\mu_*(E\setminus S)=0$ - otherwise there would exist a measurable $S'\subseteq E\setminus S$ of positive measure, giving $\mu(S\cup S')=\mu(S)+\mu(S')>\mu_*(E)$, contradicting the definition of $\mu_*(E)$. So $E\setminus S$ is a non-measurable set with inner measure zero.
Regarding the first point, given any set $E\subseteq [0,1]$ with $\mu^*(E)>0$, we can scale it to have any desired outer measure $\lambda>0$; the set
$$\tfrac{\lambda}{\mu^*(E)}E = \left\{\tfrac{\lambda}{\mu^*(E)} x \middle\vert x\in E\right\}\subseteq [0,\tfrac{\lambda}{\mu^*(E)}]$$
satisfies
$$\mu^*\left(\tfrac{\lambda}{\mu^*(E)}E\right)=\tfrac{\lambda}{\mu^*(E)}\mu^*(E)=\lambda.$$
This follows directly from your definition of the outer measure by noting that $E$ is covered by $\bigcup_{i\geq 1}[a_i,b_i]$ if and only if $\tfrac{\lambda}{\mu^*(E)}E$ is covered by $\bigcup_{i\geq 1}[\tfrac{\lambda}{\mu^*(E)}a_i,\tfrac{\lambda}{\mu^*(E)}b_i]$. By a similar scaling argument the inner measure transforms in the same way: $\mu_*\left(\tfrac{\lambda}{\mu^*(E)}E\right)=\tfrac{\lambda}{\mu^*(E)}\mu_*\left(E\right)$. So scaling does not destroy the property of having inner measure zero.