[Sorry if the following is not rigorous enough as I am an undergrad physicist with no background in pure mathematics. Please correct me if I stated something wrong or imprecisely]
In a course in Riemannian geometry, our professor gave us a definition of topological manifolds that (partly) had to do with the charts ${(U_a,\phi_a)}$ that covered the manifold and whose corresponding maps $\phi$ are homeomorphisms to $R^n$.
The professor then proceeded on to defining a differentiable manifold using the usual condition that the transition maps $\phi_a^{-1} \circ \phi_ {\beta}(W)$ with $U_{\alpha} \cap U_{\beta}=W\ne \emptyset$ need to be diffeomorphisms(homeomorphisms and $C^{\infty}$).
Now, in practice, to show that a topolgical manifold is smooth, we show the maps $\phi_{\alpha}$ are one-to-one, that the charts $(U_{\alpha},\phi_{\alpha})_{\alpha}$ cover the manifold and show that all $\phi_a^{-1} \circ \phi_ {\beta}(W)$ with $U_{\alpha} \cap U_{\beta}=W\ne \emptyset$ are diffeomorphisms.
But, since a smooth manifold is also a topological manifold, then why don't we also have to show that all the $\phi_{\alpha}$ are homeomorphisms since this is a necessary condition to have a topological manifold?
If we show this, and also show that the transition maps are $C^{\infty}$ then the transition maps are diffeomorphisms, as we want to show. But, this does not always guarantee that the maps $\phi_{\alpha}$ are homeomorphisms.
EDIT:
So, why should we just show that all the $\phi_{\alpha}$ are one-to-one? Why is it not needed to show that the coordinate maps $\phi_{\alpha}$ are onto and continuous with continuous inverse(since these along with the 1-1 condition tell us that they are homeomorphisms)?
What I said above is also true when we want to show that a topological space is a smooth manifold. So, the question is even more general.
[EDIT 2: I have edited the title due to a comment pointing out a mistake I have made. I switched from "topological manifold" to "topological space"]