Question: Is is possible to derive $\ \vdash \sim\forall xP(x) \leftrightarrow\exists x \sim P(x) \ $ (or any other version of the quantifier negation rule) axiomatically?
Context: I tutor college students in various subjects including symbolic logic. I recently acquired a new student who is using a text that I am unfamiliar with. This text is accompanied by a program called Logic 2010, so by way of preparation, I downloaded the software and began playing with it.
One of the exercises is the above derivation. However, I keep hitting an impasse when attempting it: I can't manage to derive the relationship unless I assume $\sim\exists x\sim P(x)\vdash \forall xP(x)$. Pretty much any logical rule or identity is fair game other than internal substitutions of logical equivalences.
These identities have always been presented to me as intuitively obvious, so now, I am beginning to think that it is not possible to derive them - that they must be axiomatic.
Are the quantifier negation rules axiomatic or derivable?