Having picked up a rudimentary understanding of tensors from reading mechanics papers and Wikipedia, I tend to think of rank-2 tensors simply as square matrices (along with appropriate transformation rules). Certainly, if the distinction between vectors and dual vectors is ignored, a rank 2 tensor $T$ seems to be simply a multilinear map $V \times V \rightarrow \mathbb{R}$, and (I think) any such map can be represented by a matrix $\mathbf{A}$ using the mapping $(\mathbf{v},\mathbf{w}) \mapsto \mathbf{v}^T\mathbf{Aw}$.
My question is this: Is this a reasonable way of thinking about things, at least as long as you're working in $\mathbb{R}^n$? Are there any obvious problems or subtle misunderstandings that this naive approach can cause? Does it break down when you deal with something other than $\mathbb{R}^n$? In short, is it "morally wrong"?