A function $f$ between topological spaces is sequentially continuous if the image of every convergent sequence is a sequence which converges to the image of the limit.
Continuity always implies sequential continuity: Suppose $x_n\rightarrow x$. Then if $U$ is any open neighborhood of $f(x)$, $f^{-1}(U)$ is a neighborhood of $x$ which (by continuity of $f$) is open. Because $x_n\rightarrow x$, every neighborhood of $x$ contains a tail of the sequence. In particular, $f^{-1}(U)$ contains a tail of the sequence. Hence $f(f^{-1}(U))\subseteq U$ contains the image of the tail, which is a tail of the image. Since $U$ was arbitrary, we have that every neighborhood $U \ni f(x)$ contains a tail of the image of the sequence. This means that $f(x_n)\rightarrow f(x)$.
A space is called first countable if for each point $x$, there is a countable collection of open sets around $x$ such that any set around $x$ contains some member of the collection.
In a first-countable space, the entire topology (open and closed sets) can be characterized in terms of sequences. Moreover, for functions whose domain is a first-countable space, sequential continuity implies continuity: suppose $f$ is sequentially continuous. Pick any point $x$; we will show that $f$ is continuous at $x$. Suppose $x_n\rightarrow x$. Then $f(x_n)\rightarrow f(x)$ by sequential continuity. Hence every neighborhood $U\ni f(x)$ contains a tail of the image of the sequence. Hence $f^{-1}(U)$ contains a tail of the sequence itself. We can't assume that $f^{-1}(U)$ is open (because we haven't proved that $f$ is continuous), but by first countability, we know that $f^{-1}(U)$ contains an open set $V \ni x$. We know that $V\subseteq f^{-1}(U)$, so $f(V)\subseteq U$, so $f$ is continuous at $x$.
More generally, we use the term sequential spaces to refer to the collection of topological spaces for which sequential continuity implies continuity. All first countable spaces are sequential spaces, as we have shown. And there are others: consider $\mathbb{R}/\mathbb{Z}$; the real line with its usual topology, but where the integers have been unified to a single point. You can show that this space is not first countable, but it is sequential nonetheless.
$\mathbb{R}/\mathbb{Z}$ isn't first countable: you can visualize the space as a countable number of circular loops splayed out in 3D space; the circles all meet at a single origin point 0. Each loop corresponds to an interval between integers $[n,n+1]$. The space fails to be first countable because we can't find the required countable basis for the origin point 0. For contradiction, suppose we have a collection $C$ of open sets that we want to prove is a countable basis for 0. Consider the loops of this space: how many members of $C$ does each loop contain? If $C$ is countable, there must be at least one loop $[n,n+1]$ that contains finitely many members of $C$. But then we can find a set $[n+\frac{1}{2} - \epsilon, n+\frac{1}{2} + \epsilon]$ which is smaller than the smallest such member of $C$. This set is a neighborhood of 0 but contains no member of $C$, so $C$ is not a basis for the point 0.
I don't know if there is any other surprising defining characteristic of sequential spaces besides its straightforward definition.