Others have already given the easiest examples of noncyclic subgroups of $\mathbb{C}^{\times}$.
In fact, by "polar coordinates" we have
$\mathbb{C}^{\times} \cong \mathbb{R}^{>0} \times S^1$
Each of $\mathbb{R}^{> 0}$ and $S^1$ are uncountable, hence very far from cyclic.
The point of my answer is to record my first thought upon seeing the question:
Surely every commutative group in which all proper subgroups are cyclic must be countable.
A little checking confirms that this is true. In the paper
Xu, Maoqian(PRC-GDUT-TM)
Groups whose proper subgroups are Baer groups. (English summary)
A Chinese summary appears in Acta Math. Sinica 40 (1997), no. 1, 154.
Acta Math. Sinica (N.S.) 12 (1996), no. 1, 10–17.
(it is freely available online, though I couldn't find a link that works directly)
I found
Lemma 2.1: A commutative group in which every pair of proper subgroups generates a proper subgroup is either a cyclic $p$-group or a quasi-cyclic group -- a.k.a. a Prüfer $p$-group.
Thus in an uncountable commutative group $G$, there is a proper uncountable subgroup -- otherwise every pair of proper subgroups would be countable, thus generate a countable, hence proper subgroup, and $G$ would be a cyclic $p$-group
(finite) or a quasi-cyclic group (countably infinite).
However the proof given there refers to Robinson's GTM on group theory (okay)
and a 1964 paper of Newman and Wiegold (less okay). I wonder if there is a self-contained, elementary derivation. Note though that it is also tempting to believe that any uncountable group has a proper uncountable subgroup. This was disproved by Shelah: see here.