A similar question was asked in comments elsewhere.
A paper by Roberto Di Cosmo and Thomas Dufour ("The Equational Theory of 〈ℕ, 0, 1, + , ×, ↑〉 Is Decidable, but Not Finitely Axiomatisable") asserts in footnote 2 (p.3) that it has been shown "that there are no nontrivial equations for $⟨\mathbb{N}, \mathrm{Ack}(n, \_, \_)⟩$ if $n > 2.$" References make it clear that $\mathrm{Ack}(n,x,y)=H_{n+1}(x,y)$ in the hyperoperation sequence, so the assertion is as follows:
$\text{There are no nontrivial equations for the binary function }(\_\uparrow^y\_)\text{ if }y>1\\ \text{ (i.e., for hyperoperations above exponentiation)}\tag{*}.$
(For this, the above paper cites Charles F. Martin, "Axiomatic bases for equational theories of natural numbers", Notices of the Am. Math. Soc., 19(7):778, 1972, which I have not found online.)
Q.1: What, precisely, is meant by a "nontrivial equation" here?
(The defining recursion $$x\uparrow^{y+1}(z+1)=x\uparrow^y (x\uparrow^{y+1}z),$$ which certainly holds for $y>1$, is evidently considered trivial.)
Q.2: Is the following a valid proof based on assertion $(*)$? ...
Claim:
If $x,y,z$ are integers $\gt 1$, then the value of $\ x\uparrow^y z\ $ uniquely determines $x,y,z$; i.e., $$x\uparrow^y z = x'\uparrow^{y'} z' \quad\implies\quad x=x',\ y=y',\ z=z'.\quad \tag{1}$$
(The purpose of restricting the domain to integers $>1$ is to remove obvious counterexamples that arise from equations like $x\uparrow (a\cdot z) = (x\uparrow a)\uparrow z\ \ $ or $\ \ 2\uparrow^y 2=4\uparrow^{y'} 1\ \ $ or $\ \ 1\uparrow^y z=1\uparrow^{y'} z'.$)
Proof:
Suppose, for the sake of contradiction, that there is a counterexample to $(1)$, in which the LHS of the implication holds but not the RHS. Then the LHS is a nontrivial equation for some hyperoperation(s) beyond exponentiation, which is impossible as per $(*)$. QED