Our imagination is limited. That much is a fact. We can expand it by training our minds, and slowly understand the properties of new objects to the point we are convinced that we can imagine them.
The fact that you don't have much background in abstract mathematics means that it is unlikely that you can come up with such set on your own.
Why? Well, when we think about sets of real numbers we think about intervals, this is because intervals are nice. They are defined by two endpoints and that's that. We could maybe think about a finite union of intervals, which is again defined by a few (read: finitely many) points and that's that.
However can you imagine the rationals? Can you imagine the rationals and discern them, in your imagination, from the irrationals or the real numbers? Can you imagine the irrational numbers? Can you discern this set from the entire real numbers? It takes some experience to understand those set to begin with, let alone to imagine them, and even more time to come up with similar examples on your own.
The rational and irrational numbers are both very simple sets in terms of "description", namely if we look at the Borel sets, they are generated from the intervals by unions, complements, and intersections. We can assign each set some sort of complexity rank -- how many steps we need to do before we can generate it from the intervals themselves. Both the rationals and irrationals are quite simple. The Borel sets themselves are vastly more complicated, and in fact you cannot even imagine Borel sets which are very complicated. At least not without understanding a lot more about this.
All that is fine, but one can easily use the way we define the Borel sets to show that in fact there are only $2^{\aleph_0}$ Borel sets. Cantor's theorem, however, tells us that there are $2^{2^{\aleph_0}}$ sets of real numbers and that this is a much larger number of sets. In particular almost all sets of real numbers are not Borel.
To your specific question, it is difficult to give an example of a concrete non-Borel set, in particular because we need to use something called the axiom of choice in order to prove the existence of such sets. The axiom of choice is a useful tool in modern mathematics whose power is in its non-constructiveness, namely we can use it to prove that a certain object exists without demonstrating an example for such object. For example, we can prove that there are non-Borel sets, but we cannot really point out at a set and say it is a non-Borel set. While there are examples of sets which are not Borel sets, such as the one linked by jkl in the comments (see: Constructing a subset not in $\mathcal{B}(\mathbb{R})$ explicitly), we still have to use the axiom of choice to prove that this set is not a Borel set.