I am having trouble seeing how to apply the definition of transcendental to see this. Thanks!
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5Suppose $\pi$ has a multiplicative inverse, and see what happens. – Chris Eagle Oct 31 '12 at 21:21
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4In general, for $\alpha \in \mathbb C$, we have $\mathbb Q[\alpha]$ is a field iff $\alpha$ is algebraic. – lhf Oct 31 '12 at 21:26
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If $\mathbb{Q}[\pi]$ were a field, then $\pi$ would have an inverse. Every element in $\mathbb{Q}[\pi]$ is of the form $r_0+r_1\pi+r_2\pi^2+\cdots+r_n\pi^n$. So an inverse of $\pi$ would cause $(r_0+r_1\pi+r_2\pi^2+\cdots+r_n\pi^n)\pi=1$. But this is not possible, as this would imply $\pi$ is root of a polynomial with rational coeefficients, which it is not (it is transcendental).

Fredrik Meyer
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Hint $\ $ Notice $\:\pi\:$ transcendental over $\rm\Bbb Q\:\Rightarrow\:\Bbb Q[\pi]\cong \Bbb Q[x].\:$ But a polynomial ring cannot be a field since if $\rm\ x^{-1}\! = f(x)\in\Bbb Q[x]\ $ then $\rm\ x \; f(x) = 1 \: \Rightarrow\: 0 = 1,\ $ by evaluating at $\rm\ x = 0. $
Remark $\ $ The above proof has a very instructive universal interpretation.

Bill Dubuque
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Very clean. Would an isomorphism between the two rings be given by the map $\varphi(\pi) = x$, and $ \varphi(q) = q$ for all other $q \in \mathbb Q[\pi]$? – Moderat Nov 01 '12 at 02:58
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@jmi4 The kernel of the evaluation hom $\rm: x\to \pi:$ from $\rm:\Bbb Q[x]:$ onto $\rm:\Bbb Q[\pi]:$ is the ideal of polynomials $\rm:f\in\Bbb Q[x]:$ with $\rm:f(\pi) = 0;:$ if it contained any $\rm:f \ne 0:$ then $,\pi,$ would be algebraic over $,\Bbb Q.,$ Thus $\rm:f = 0,,$ i.e. the evaluation map has kernel $= 0,:$ so it is an isomorphism. Informally: any transcendental element serves as an indeterminate. – Bill Dubuque Nov 01 '12 at 03:51