I'm reading a paper now that works with operators on the vector space of real $d\times d$ matrices (such an operator can be thought of as a 4-dimensional tensor). The definition of positive-definiteness in this setting would seem to be the analogue of the usual one: we have the standard inner product $\langle A,B\rangle = \text{tr}(A^TB)$ and we say the operator $\mathcal{M}$ is positive-definite if for all matrices $A$ we have $\text{tr}(A^T\mathcal{M}A)>0$.
However, the definition this paper uses is that the above holds for all symmetric matrices $A$. What's the difference (if any?)? Why should this be the right definition (and is it?)?
More generally, is there a good reference on linear algebra over such spaces with special structure as the space of matrices?