I found that the Fibonacci numbers $F_n$, taken$ \bmod n$, have the property that, for prime $n\ne 5$, $F_{n-1}$ and $F_{n+1}$ are $0$ and $1$, with the order depending on the value of $n\bmod 5$.
So if prime $n\equiv \pm 1\bmod 5$, $F_{n-1}\equiv 0$ and $F_{n+1}\equiv 1 \bmod n$
If prime $n\equiv \pm 2\bmod 5$, $F_{n-1}\equiv 1$ and $F_{n+1}\equiv 0 \bmod n$
It also turns out this is a fairly reliable test of whether $n$ is prime - that is, there are not many composites passing the test. The first composite number to masquerade as a prime is $4181$, then $5777, 6721, 10877, 13201, 15251$ are the remaining pseudoprimes under $20000$. This sequence is listed under OEIS A212424.
What I haven't been able to do is prove that this property does in fact hold for prime numbers. Can anyone produce a proof of the correctness of this relation?
Greg Martin gave some useful terminology:
The first positive integer $m$ for which $F_m\equiv 0 \bmod n$ is called the "rank of apparition" of $n$
Then ($\equiv \bmod n$) the "apparition multiplier" (my term) $k:\equiv F_{m-1}\equiv F_{m+1}\equiv F_{m+2}$ means that $F_{i+m}\equiv k F_i$ and $F_{i+jm}\equiv k^j F_i$. $k$ must be coprime to $n$ because the Fibonacci sequence can be generated in reverse so some $d\ne 1$ that divides both $k$ and $n$ would preclude $F_1=1$ (since $d$ would divide every element). This guarantees that $F_s\equiv 0 \Rightarrow m\mid s$ and that since at some point $k^j\equiv 1$, we will have the period $r, \bmod n$.
For the result above on primes we need $r\mid n{-}1$ in the first case and $m\mid n{+}1, r\mid 2(n{+}1)$ in the second case.
I was still thinking about what values the rank of apparition $m$ can take and working through http://www.fq.math.ca/Scanned/1-2/vinson.pdf .