In How do we prove that something is unprovable? it was answered:
All proofs of the Pythagorean Theorem rely essentially on the Parallel Postulate; so if you try to prove what you can in geometry with the Parallel Postulate omitted (this is called 'absolute geometry'), then the Pythagorean Theorem becomes an unprovable theorem within that context. (this is about the only situation where I think the phrase 'uprovable theorem' is the natural choice)
Is it also possible to take the Pythagorean Theorem as an axiom of geometry and prove the Parallel Postulate as a theorem?