The field $\mathbb{F}$ is the collection of scalars associated with the vector field. The most common examples of vector spaces are over $\mathbb{R}$ or $\mathbb{C}$, but for many theorems in linear algebra, the only important algebraic properties that the scalars must have are the properties of a field ($\mathbb{R}$ and $\mathbb{C}$ have additional analytic properties).
You use this field in the definition of a vector space when you define scalar multiplication: a map $\mathbb{F} \times V \to V$ which sends $(\alpha,v)$ to the multiplication of $v$ by $\alpha$, written $\alpha v$. Consequently, if you choose a basis, then $V$ can be viewed (in the finite-dimensional case, at least) as column vectors with elements in $\mathbb{F}$, in the same way that an $n$-dimensional real vector space may be viewed as $\mathbb{R}^{n}$ when a basis has been chosen.
For a simple example of using a different field, we can take, say, $\mathbb{F}_{2}^{n}$, which would be all column vectors whose components are only $0$ or $1$.
For a more interesting example: $\mathbb{R}$ can be viewed as an infinite dimensional vector space over the rationals $\mathbb{Q}$.