I think there is some confusion here.
ZF-Inf+$\neg$ Inf certainly does prove some theorems that ZF-Inf alone doesn't - namely, $\neg$ Inf! Keep in mind that every model of ZF is also a fortiriori a model of ZF-Inf.
Now, you write:
The universe of discourse for both [theories] is $V_\omega$.
I don't really know what you mean here. It is true that $V_\omega$ is the minimal model of each theory - however, that doesn't make it the universe of discourse, or even the intended model, of either.
I suspect you are asking about whether ZF-Inf and ZF-Inf+$\neg$Inf prove different things about arithmetic. The answer to this is no:
For any model $M$ of ZF-Inf, the susbtructure $(V_\omega)^M$ is a model of ZF-Inf+$\neg$Inf.
This is a straightforward verification.
You then ask:
More importantly, if $PRA$ + $TI({\epsilon_0})$ can prove the consistency of $ZF$ $-$ Inf, is there a way to consistently add Inf as a new axiom to $ZF$ $-$ Inf (say, by showing that Inf is independent of $ZF$ $-$ Inf--has this been done already)? If not, where do the problems with this 'bootstrapping' approach to the proof of the consistency of $ZF$ lie?
Well, "Inf is independent of ZF-Inf" is just a complicated way of saying "ZF is consistent"; and this is definitely provable from the right axioms e.g. ZF+large cardinals. I presume you're asking about whether $PRA$ + $TI({\epsilon_0})$ can prove this. In that case, the answer is of course "no": e.g. ZF proves that $PRA$ + $TI({\epsilon_0})$ is consistent! Indeed the consistency of ZF is galactically beyond the abilities of $PRA$ + $TI({\epsilon_0})$, so if $PRA$ + $TI({\epsilon_0})$ proved "ZF is consistent" then $PRA$ + $TI({\epsilon_0})$ would be inconsistent, by Goedel's Second.
(In detail: the key point is that $PRA$ + $TI({\epsilon_0})$ proves that ZF proves every true $\Sigma_1$ sentence, so in particular $PRA$ + $TI({\epsilon_0})$ proves that if $PRA$ + $TI({\epsilon_0})$ is inconsistent, then ZF proves that $PRA$ + $TI({\epsilon_0})$ is inconsistent; and moreover, since $PRA$ + $TI({\epsilon_0})$ proves every true $\Sigma_1$ sentence, $PRA$ + $TI({\epsilon_0})$ proves that ZF proves that $PRA$ + $TI({\epsilon_0})$ is consistent (since ZF does in fact prove this). So combining these two points, $PRA$ + $TI({\epsilon_0})$ proves "If ZF is consistent, then $PRA$ + $TI({\epsilon_0})$ is consistent" - so $PRA$ + $TI({\epsilon_0})$ better not prove that ZF is consistent! See this question for more analysis along these lines.)
I get the sense that you're trying to extend the Ackermann interpretation to get hold of more powerful theories than ZF-Inf+$\neg$Inf. As I explained in my answer to your other question, however, there is a serious obstacle to this: since the Ackermann interpretation satisfies $$(*)\quad\mbox{If $m$ codes a set containing $n$, then $m>n$},$$ the Ackermann structure associated to a model of PA will always satisfy $\neg$Inf. In particular, if you want a method for coding some models of ZF into models of PA which goes beyond just models of ZF-Inf+$\neg$Inf, then your coding method will need to be vastly more complicated.