We assume that $\mathbb{R}$ is a totally ordered field $(\mathbb{R},+,\cdot,\leq)$. We define $x < y$ to be "$x \leq y$ and $x \neq y$".
I will assume the following properties:
$\quad$(TO1)$\quad$ For any $x$ and $y$, either $x \leq y$ or $y \leq x$ (or both).
$\quad$(TO2)$\quad$ ($x \leq y$ and $y \leq z$) $\implies$ $x+z \leq y + z$.
$\quad$(TO3)$\quad$ ($x \leq y$ and $0 \leq z$) $\implies$ $xz \leq yz$.
$\quad$(F1)$\quad$ For any $x$ we have that $1 \cdot x = x$.
$\quad$(F2)$\quad$ For any $x$ we have that $0 \cdot x = 0$.
$\quad$(F3)$\quad$ For any $x$ we have that $0 + x = x$.
$\quad$(F4)$\quad$ $0 \neq 1$.
$\quad$(F5)$\quad$ $1$ has an additive inverse, $-1$, i.e. $1 + (-1) = 0$.
Assume that $0 \not< 1$. From (F4) we know that $0 \neq 1$, hence $0 \not\leq 1$. Then from (TO1) we have that $1 \leq 0$. Again, since $1 \neq 0$, we now know that $1 < 0$.
Because our field is totally ordered, we have
$$1 < 0 \implies 1 + (-1) < 0 + (-1) \implies 0 < -1,\tag{1}$$
where I used (TO2) in the first step, and (F5) and (F3) in the second step.
But since $0 < -1$, we also have that
$$ 1 < 0 \implies 1 \cdot (-1) < 0 \cdot (-1) \implies -1 < 0,\tag{2}$$
where I used (TO3) in the first step, and (F1) and (F2) in the second step.
Equations $(1)$ and $(2)$ together pose a contradiction.
Note: Properties (F2) and (F4) you may still have to prove yourself.