Intuitively, as long as $f'(x)$ attains its minimum at one single point, there won't exist two distinct points where the secant matches that slope.
To formalize, assume $f'(x)$ has a global minimum $m$, then it follows from MVT that:
$$\frac{f(b)-f(a)}{b-a} \ge m \quad \text{for} \;\;\forall a \ne b$$
If $a,b$ points exist where the equality holds, then by MVT for the intervals $(a,\frac{a+b}{2})$ and $(\frac{a+b}{2},b)$:
$$m = \frac{f(b)-f(a)}{b-a} = \frac{1}{2}\left(\frac{f(b)-f(\frac{a+b}{2})}{\frac{b-a}{2}} +
\frac{f(\frac{a+b}{2})-f(a)}{\frac{b-a}{2}}\right) \ge \frac{1}{2}(m+m) = m
$$
It follows that the middle inequality must be an equality as well, so:
$$m = \frac{f(b)-f(a)}{b-a} = \frac{f(b)-f(\frac{a+b}{2})}{\frac{b-a}{2}} = \frac{f(\frac{a+b}{2}) - f(a)}{\frac{b-a}{2}}
$$
From which:
$$f\left(\frac{a+b}{2}\right) = \frac{f(a) + f(b)}{2}$$
It follows that $f(x)$ is both midpoint convex and concave, thus linear by continuity (see for example Function that is both midpoint convex and concave). But the given $f(x)$ is a $3^{rd}$ degree polynomial which is obviously not linear, so such points $a,b$ do not exist. Therefore the strict inequality holds.