First, if you're just looking around online, you should try the coupon collector's problem. In its canonical form, the coupon collector's problem is to calculate the expected number of picks until all the coupons (or items in your box) are labelled. Your problem has the tables turned. You want to calculate the expected number of coupons (items) labelled in a specified number of picks.
Second, I think it's worth pointing out the bull-headed approach to this problem and why it doesn't work! In the bull-headed approach, the expectation of a discrete random variable $X$ is $\sum_m m\cdot\text{prob}(X=m)$. In this problem we need the probability that in $w$ rounds exactly $m$ items get labelled, a computation that requires some work. First, you can choose $m$ items among the entire collection of $n$, and there are $\binom n m$ ways to make this choice. Then you need to count the number of onto functions from the rounds $\overline{w}=\{1,\dots,w\} $ to the selected items $\overline{m}=\{1,\dots,m\}$. This is equivalent to selecting all $m$ items in the $w$ rounds. Using a well-known argument from the inclusion-exclusion principle, it turns out that there are
$$\sum_{j=0}^m (-1)^j\binom m j(m-j)^w$$
onto functions from $\overline{w}$ to $\overline{m}$. Finally, you have to compare these onto functions with the total number of functions from $\overline{w}$ to $\overline{m}$, which is just $m^w$. Putting all this together, the expected number of items labelled in $w$ rounds is
$$\sum_{m=1}^n m\binom n m \sum_{j=0}^m (-1)^j\binom m j(m-j)^w\big/m^w.$$
The problem with this method is that I certainly don't know how to get a closed-form expression for the double sum representing the expectation. (For that matter, neither does Maple.) This impasse highlights the elegance of the solution that Henry suggested. Also, it makes me interested in seeing a cleaned-up version of the "bull-headed" method that produces the same expected number of items that Henry got in his elegant solution, namely $n\bigl(1-(1-\frac1n)^w\bigr)$.