In what follows, let $\sigma_p$ be the standard p-simplex in $\mathbb{R}^{p+1}$. This question is inspired by the following quote from Vick's Homology Theory, p.3:
Let $X$ be a topological space. A singular p-simplex in $X$ is a continuous function $$\phi: \sigma_p \to X.$$ Note that singular 0-simplices may be identified with the points of $X$, the singular 1-simplices with the paths in $X$, and so forth [emphasis mine].
This immediately made me wonder if singular 2-simplices may be identified with the homotopies of $X$. Now obviously the standard 2-simplex is homeomorphic to $[0,1]\times[0,1]$, so there exists a continuous map $\psi: [0,1]\times[0,1]\to\sigma_2$, and thus by composition, for any singular 2-simplex $\phi:\sigma_2\to X$, we automatically have a continuous map $\phi\circ\psi:[0,1]\times[0,1]\to X$.
However, in order for this to be a homotopy, we need additionally that the maps $\phi\circ\psi(0,-):[0,1]\to X$ and $\phi\circ\psi(1,-):[0,1]\to X$ be constants (at least according to the definition of homotopy given in Hatcher's Algebraic Topology).
Question: does there exist such a continuous map $\psi:[0,1]\times[0,1]\to \sigma_2$ which satisfies these two additional conditions?
EDIT: This page claims that we can replace continuous maps from the standard $k-$simplex with continuous maps from the closed $k-$ball, although it makes the mistake of saying that $\phi$ has to be a homeomorphism (it just has to be continuous), and it doesn't mention $[0,1]^k$ ($k-$cubes) at all, which would be necessary to define a $k-$homotopy.
This page also states the claim that singular 1-simplices can be identified with paths, and it says that
We could generalize the fundamental group by taking homotopy classes of singular $n-$simplices in $X$, and making an appropriate definition of the 'product' of two singular simplicies. This can indeed be done, but the resulting groups are the homotopy groups $\pi_n(X)$.
This would seem to corroborate my suspicion that singular $2-$simplices are either related or equivalent to the set of all path homotopies in $X$, but I am not really sure.
This webpage claims that singular 0-simplices can be identified with points, and that singular 1-simplices can be identified with paths, but it says "Fill this in later" for singular 2-simplices.
This webpage states that singular $n-$simplices generalize paths in $X$, but it doesn't clarify how, specifically whether this generalization is the same as homotopies. Although it does say that "this construction... is one of the classical approaches to determining invariants of the homotopy type of the space". And it says that the singular simplicial complex of $X$ is its nerve.
This document gives a nice intuition of how in other contexts homotopies are a natural generalization of points and paths to higher dimensions.