Here's what I have so far:
$$\sqrt{a}-\sqrt{b} = m/n \implies a^2 + b^2 -2\sqrt{ab} = (m/n)^2$$ Therefore, $\sqrt{ab}$ must be rational, $ab$ must be a perfect square. Also,
$$\left(\sqrt{a}-\sqrt{b}\right)\left(\sqrt{a}+\sqrt{b}\right) = a - b$$
Therefore, in order for $\sqrt{a}-\sqrt{b}$ to be rational, $\sqrt{a}+\sqrt{b}$ must also be rational for all $a$ and $b$ such that $a \neq b$.
Is this a good enough answer?