I can easily see how to construct non trivial automorphisms of an algebraic extension of $\mathbb{Q}$, for example in $\mathbb{Q}(\sqrt{5})$, the isomorphism $\phi$ fixing the rationals and sending $\sqrt{5}$ to $-\sqrt{5}$, coming from the fact that $\phi (5) = \phi (\sqrt{5} \sqrt{5}) = \phi (\sqrt{5})^2 = 5$ and hence, $\phi (\sqrt{5}) = - \sqrt{5}$ is a possibility.
But I'm having troubles seeing a non trivial automorphism in a transcendental one, like $\mathbb{Q}(\pi)$. Where should it send $\pi$ ? any help ?