Note that $p|3$ implies $p=3$ (as dxiv said). So, the problem is equivalent to the following statement:
Prove that if $p = 4k-1$ is a prime dividing $m^2+9$, then $p=3$.
Furthermore, we may notice that if $3|m^2+9$, $3|m$, so $p|m$. Thus, it suffices to prove:
The only prime $p\equiv 3\mod 4$ that can divide $m^2+9$ is $p=3$.
We will prove this using the notion of quadratic reciprocity.
Let $p$ be a prime $p \equiv 3\mod 4, p\neq 3$, and assume for the sake of contradiction that $p|m^2+9$ for some $m$, or equivalently that $m^2 \equiv -9 \mod p$. That would mean that
$$\left(\frac{-9}{p}\right) = 1$$
where $\left(\frac{a}{p}\right)$ is a Legendre Symbol, which is $1$ if $a$ is a quadratic residue mod $p$ and $-1$ otherwise. Using the property that
$$\left(\frac{a}{p}\right)\left(\frac{b}{p}\right) = \left(\frac{ab}{p}\right)$$
we get that
$$\left(\frac{-9}{p}\right) = \left(\frac{-1}{p}\right)\left(\frac{9}{p}\right)$$
Since $9$ is obviously a quadratic residue modulo any prime $p$, $\left(\frac{9}{p}\right) = 1$, so we reduce our condition to
$$\left(\frac{-1}{p}\right) = 1$$
This Legendre symbol is well known to be $1$ is $p\equiv 1\mod 4$ and $-1$ is $p\equiv 3\mod 4$, so we get a contradiction.
Note that this line of reasoning fails for $p=3$ since $\left(\frac{-9}{3}\right)$ is not $1$ or $-1$ by the way the Legendre symbol is defined. These manipulations do not work when the denominator of the Legendre symbol divides the numerator.