A few things to note:
1) There are integer solutions to $Kx + My = Z$ if and only $\gcd(K,M) | Z$. BUT these solutions might have negative integer values.
$\gcd(13,7) = 1$ and $1$ divides everything so a) and b) have solutions but they may b be negative solutions which are not acceptable for monetary transactions.
2) To determine possible solutions for $Kx + My = Z = Z'\gcd(K,M)$:
It suffices the assume $\gcd(M,) = 1$ as $Kx + My = Z'\gcd(K,M)$ will have the exact same solutions as $\frac {K}{\gcd(K,M)}x + \frac{M}{\gcd(K,M)} = Z'$.
It also suffices to assume $K \not \mid Z$ so as $K\frac{Z}K + M*0 = Z$ would be a trivial and obvious solution.
So we will assume if $Kx + My = Z$ then $x \ne 0$ and $y \ne 0$.
If $Kx + My = Z$ is a solution so is $K(x \pm Mj) + M(y \mp Kj) = Z$.
If $Kx + My =Z$ and $Kx' + My' = Z$ are two solutions then $Kx = Z - My$ so $My \equiv Z \mod K$. Likewise $My' \equiv Z \equiv My \mod K$. As $\gcd(M,K) = 1$ it follows $y \equiv y' \mod K$.
And obviously we can do the same for $x$. $x \equiv x' \mod M$ for the exact same reasons.
So $K(x \pm Mj) + M(y \mp Kj) = Z$ are the only solutions and we can find these solutions by solving $My \equiv Z \mod K$ and $Kx \equiv Z \mod M$.
So for example:
a) $7a + 13b = 71$ will have solution when $13b \equiv 71 \mod 7$ so $-b \equiv 1 \mod 7$ so $b \equiv -1 \mod 7$. So $b = -1$ and $7a -13 = 71 \implies a=12$ will be a solution.
$7*12 + 13(-1) = 71$ is a solution. But it is not an acceptable non-negative solution.
b) $7a + 13b = 75$ will have a solution when $13b \equiv 75 \mod7$ so $-b \equiv 5 \mod 7$ so $b \equiv -5 \mod 7$. So $b = -5$ and $7a - 13*5 = 75 \implies $a = 20$ will be a solution.
$20*7 - 5*13 = 75$ is a solution but not positive.
3) Finding positive solutions (if any).
If $K(u+Mj) + M(w- Kj) = Z$ are sets of solutions. $u + Mj \ge 0$ if $j \ge -u/M$. $w - Kj \ge 0$ if $j \le w/K$. If there exists $-u/M \le j \le w/K$ then there will be all positive solutions for each possible $j$. Otherwise there will not be.
So for a)
$7*12 - 13*1 = 71$. We want $7(12 - 13j) + 13(-1 + 7j)= 71$ and we want $1/7 \le j \le 12/13$. There are no such $j$ and so no positive solutions.
So for b)
We want $7(20 - 13k) + 13(-5 + 7k) = 71$. So we want $5/7 \le k \le 20/13$. There is exactly one such $k$ ($k = 1$) so the only positive solution is:
$7(20 - 13) + 13(-5 + 7) = 7*7 + 13*2 = 71$.