According to Wikipedia, the definition of the Lebesgue outer measure of a set $E$ is as follows:
$$ \lambda^*(E) = \operatorname{inf} \left\{\sum_{k=1}^\infty l(I_k) : {(I_k)_{k \in \mathbb N}} \text{ is a sequence of open intervals with } E\subseteq \bigcup_{k=1}^\infty I_k\right\} $$
Suppose we remove the countability requirement: $$ \lambda^*(E) = \operatorname{inf} \left\{\sum_{I \in X} l(I) : X \text{ is a set of open intervals with } E\subseteq \bigcup_{I \in X} I\right\} $$
(Where we could just define $\sum_{I \in X} l(I)$ to be $\operatorname{sup} \left\{\sum_{I \in Y} l(I) : Y \text{ is a finite subset of } X \right\}$.)
Why would this not work? What would break if we remove the countability requirement?