Suppose that the first ball drawn is white and that you stop on draw number $2k$. Then the $2k$-th ball drawn was black, and the $2k-2$ balls drawn in positions $2$ through $2k-1$ form a Dyck word of length $2k-2$. Conversely, any sequence of $2k-2$ white and black balls in which the number of black balls never exceeds the number of white balls can occupy those $2k-2$ positions. Thus, there are $C_{k-1}$ sequences of draws beginning with a white ball that terminate with draw $2k$. If we imagine continuing until the bin is empty, there are $\binom{2n-2k}{n-k}$ ways to complete the draw, for a total of $C_{k-1}\binom{2n-2k}{n-k}$ full draws that start with a white ball and first balance (at equal numbers of white and black balls) on draw $2k$. There is an equal number starting with a black ball, so
$$2C_{k-1}\binom{2n-2k}{n-k}=\frac2k\binom{2k-2}{k-1}\binom{2n-2k}{n-k}$$
of the $\binom{2n}n$ possible full draws first balance on draw $2k$. The expected number of draws to the first balanced sample is therefore
$$\binom{2n}n^{-1}\sum_{k=1}^n\frac2k\binom{2k-2}{k-1}\binom{2n-2k}{n-k}(2k)=4\binom{2n}n^{-1}\sum_{k=1}^n\binom{2k-2}{k-1}\binom{2n-2k}{n-k}\;,$$
and your conjecture is equivalent to
$$4^{n-1}=\sum_{k=1}^n\binom{2k-2}{k-1}\binom{2n-2k}{n-k}=\sum_{k=0}^{n-1}\binom{2k}k\binom{2n-2k-2}{n-k-1}$$ or, after replacing $n-1$ by $n$, to
$$4^n=\sum_{k=0}^n\binom{2k}k\binom{2n-2k}{n-k}\;.$$
You can find a proof of this identity in this question together with an outline of a combinatorial proof; this answer gives a full combinatorial proof.