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In which topological and metric spaces are the sigletons $G_δ$, and why? One example is $(\mathbb{R},|\cdot|)$, or the Euclidean multidimensional metric space. Thank you.

AfterMath
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Singletons are $G_\delta$'s in a first countable $T_1$ space. That is, for any $x$ there is a sequence $B_n$ of neighbourhoods of $x$ such that every neighbourhood of $x$ contains some $B_n$. For any $y \ne x$, since the complement of $\{y\}$ is a neighbourhood of $x$ there is some $B_n$ that doesn't contain $y$, and so $\cap_n B_n = \{x\}$.

An example of a space that doesn't have this property is the cofinite topology on an uncountable set.

EDIT: A space in which singletons are $G_\delta$'s must be a $T_1$ space, but need not be first countable. A counterexample is the quotient space $\mathbb R/\mathbb N$ (i.e. take the reals and identify all natural numbers as the same point).

Robert Israel
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    @user359315: As a very limited partial converse, if $X$ is a compact Hausdorff space or a subspace of a linearly ordered space, then singletons are $G_\delta$ sets iff $X$ is first countable. – Brian M. Scott Aug 05 '16 at 13:56