Suppose that $n$ has an odd prime divisor. Then
$$
\phi(n)=n\prod_{p\mid n}\frac{p-1}{p}=\frac{n}{\prod_{p\mid n}p}\cdot \prod_{p\mid n}(p-1).
$$
Both factors are integers, and the second factor is even, because $p-1$ is even for our odd prime divisor $p$. Hence $\phi(n)$ is even, so different from $5$. Now we consider the remaining case, that $n$ has no odd prime divisor. Then $n=2^r$. For $r=1$ we have $\phi(n)=\phi(2)=1$, and for $r\ge 2$ we have $\phi(n)=2^r-2^{r-1}$, which is even, so different from $5$.
Summarizing we can say that there is no $n$ with $\phi(n)=5$ (or any other odd number greater than $1$, for that matter).