The first equation can be interpreted combinatorically as: The number of subsets of a set with $n$ elements (i.e. $2^n$) is equal to the sum of the numbers of $k$-element subsets of the set (i.e. $\binom{n}{k}$). This statement is somewhat trivial: If you count all subsets of size $k$ and do this for every $k\in\{0,\dots,n\}$, then you are counting all subsets (each exactly once).
If you want a more technical proof, apply the binomial theorem which gives us
$$2^n = (1+1)^n = \sum_{k=0}^{n}\binom{n}{k}1^n1^{k-n} = \sum_{k=0}^{n}\binom{n}{k}.$$
For the second equation, we may use the binomial theorem again:
$$n2^{n-1} = n(1+1)^{n-1} = n\sum_{k=0}^{n-1}\binom{n-1}{k}1^{n-1}1^{k-n+1} = \sum_{k=0}^{n-1}n\binom{n-1}{k} = \sum_{k=0}^{n-1}(n-k)\binom{n}{k} = \sum_{k=0}^{n-1}(n-k)\binom{n}{n-k} = \sum_{k=1}^{n}k\binom{n}{k}.$$
Note that we have used $n\binom{n-1}{k} = n\frac{(n-1)!}{k!(n-k-1)!} = \frac{n!}{(n-k-1)!k!} = (n-k)\frac{n!}{(n-k)!k!} = (n-k)\binom{n}{k}$, as well as $\binom{n}{k}=\binom{n}{n-k}$. The last step of the equation follows from turning around the order of summation.