The continuum hypothesis can be formulated in two different ways:
- $2^{\aleph_0}=\aleph_1$,
- $A\subseteq\mathbb R$ then either $|A|\leq\aleph_0$ or $|A|=|\mathbb R|$.
It is clear that in ZFC both those statements are equivalent, but this is not the case in ZF.
However if we assume that $2^{\aleph_0}\geq\aleph_2$ then both these formulations are provably false, because it means that there is a set of real numbers which is of size $\aleph_1$ and the real numbers themselves have at least $\aleph_2$ many elements. In this case this statement is false in ZF and in ZFC.
Generally speaking, ZF and ZFC are theories, we can talk about provability; for a statement to be true we have to talk about a model. For example, AC itself is true in a model of ZFC which is a model of ZF, but it is not provable from ZF.
If a statement is provable from ZF, then it has to be provable from ZFC, we only added an axiom, so we did not make provable into unprovable or provably false. Equally, if something is provably false from ZF then it will remain provably false in ZFC.
To add a bit on the point in tomasz' answer:
It was proved by Gödel that if ZF is consistent then ZF+GCH+AC is consistent (in particular ZF+$2^{\aleph_0}=\aleph_1$ is consistent). However Cohen invented the method of forcing and used it to prove that if ZFC+GCH is consistent then ZF+$2^{\aleph_0}=\aleph_2$ is consistent.
This means that we cannot prove from ZFC alone what is the exact $\alpha$ such that $2^{\aleph_0}=\aleph_\alpha$. Namely, we cannot prove that it is $\aleph_1$ or $\aleph_2$ or higher. In fact we can make it arbitrarily high $\alpha$. Furthermore we cannot even prove from ZF that such $\alpha$ exists at all.
In order to have a theory strong enough to prove what is the exact cardinal of the continuum we need to have more axioms than merely ZFC.