Enforce the substitution $x\to \log(x)$ and write
$$\int_0^\infty xe^{-x}\,dx=\int_1^\infty \frac{\log(x)}{x^2}\,dx$$
Then, note that for any $\alpha>0$ and $x\ge 1$, we have
$$0\le \log(x)\le \frac{x^{\alpha}-1}{\alpha} \tag 1$$
Can you finish?
NOTE:
To establish the inequalities in $(1)$, we use the result from THIS ANSWER in which I showed using only the limit definition of the exponential function and Bernoulli's Inequality that the logarithm function satisfies the inequalities
$$\frac{z-1}{z}\le \log(z)\le z-1 \tag 2$$
for $z>0$. Now, since
$$\log(x^\alpha)=\alpha \log(x)$$
we establish the right-hand side inequality of $(1)$ by letting $z=x^\alpha$ in $(2)$ using $(3)$, and dividing by $\alpha>0$.
The left-hand side inequality of $(1)$ is true since $\log(x)$ is monotonically increasing with $\log(1)=0$.