For the first question, let $X=\ell_\infty$. For $n\in\Bbb N$ let $x_n\in X$ be defined by $$x_n(k)=\begin{cases}1,&\text{if }k=n\\0,&\text{otherwise}\;,\end{cases}$$ and let $$V_n=\left\{y\in X:\|y-x_n\|<\frac14\right\}\;.$$ Let $y\in X$ and $B=\{z\in X:\|y-z\|<1/4\}$, and suppose that $B\cap V_n\ne\varnothing$. Then there is a $z\in X$ such that $\|z-y\|<1/4$ and $\|z-x_n\|<1/4$, so $\|y-x_n\|<1/2$. If $\|y-x_m\|<1/2$ as well, then $\|x_n-x_m\|<1$, and therefore $m=n$. Thus, $\mathscr{V}=\{V_n:n\in\Bbb N\}$ is a locally finite family of open sets.
Let $f_n:X\to\Bbb R$ be any continuous function such that $f(x_n)=n$ and $f(y)=0$ for $y\in X\setminus V_n$. Finally, let $f=\sum_{n\in\Bbb N}f_n$. Since $\mathscr{V}$ is locally finite, $f$ is a continuous function from $X$ to $\Bbb R$, and clearly $f$ is unbounded on the unit ball.